2-Ethyl-6-(2-pyridyl)-5,6,6a,11b-tetrahydro-7H-indeno[2,1-c]quinoline

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2-Ethyl-6-(2-pyrid­yl)-5,6,6a,11b-tetra­hydro-7H-indeno[2,1-c]quinoline

The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels-Alder reaction via a one-pot condensation between anilines, α-pyridine-carboxy-aldehyde and indene using BF(3)·OEt(2) as the catalyst. The mol-ecular structure reveals the cis-form as the unique diastereoisomer. The crystal structure comprises one-dimensional zigzag ribbons connected via N-H⋯N hydrogen bonds....

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Ethyl 2-(3-chloro-2-pyridyl)-5-oxopyrazolidine-3-carboxylate

In the mol-ecule of the title compound, C(11)H(12)ClN(3)O(3), the five membered ring adopts an envelope conformation. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers.

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Crystal structure of 2-[(5',6',7',8'-tetrahydro-5',5',8',8'-tetramethyl)-2'-naphthyl]-1-ethyl-1H-benzimidazole-5-carboxylic acid ethyl ester.

retinoids with a tetrahydronaphthalene structure (Fig. 1), was synthesized using an NaHSO3 addition product of 5,6,7,8tetrahydro-5,5,8,8-tetramethyl-2-naphthalene-carboxaldehyde (compound I) as a starting material, which was prepared as described.1 The condensation of compound I and 4-ethylamino3-amino-ethylbenzoate (mp: 73 ̊C) in DMF for 70 h gave the title compound (recrystallized from hexane/...

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trans-Dichloridobis[(6-nicotinoyl-2-pyridyl-κN 6)(3-pyridyl-κN)methanone]copper(II)

In the title complex, [CuCl(2)(C(17)H(11)N(3)O(2))(2)], the Cu(II) ion is located on an inversion center. It exhibits a distorted octa-hedral coordination geometry defined by two chloride anions at trans sites and four 3-pyridyl N atoms at equatorial sites from two (6-nicotinoyl-2-pyrid-yl)(3-pyrid-yl)methanone ligands. The (6-nicotinoyl-2-pyrid-yl)(3-pyrid-yl)methanone ligand can be viewed as ...

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N-Ethyl-2-[1-(2-hy­droxy-6-meth­oxy­phenyl)ethyl­idene]hydrazinecarbothio­amide

In the title compound, C(12)H(17)N(3)O(2)S, the dihedral angle between the mean planes of the hydrazinecarbothio-amide group and the benzene ring is 86.8 (4)°. In the crystal, inter-molecular O-H⋯S hydrogen bonds link the mol-ecules into chains along [001]. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.98021 (3):0.01978 (7).

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810005805